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Methane

Methane (US: /ˈmɛθn/ METH-ayn, UK: /ˈmθn/ MEE-thayn) is a chemical compound with the chemical formula CH4 (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is hard because it is a gas at standard temperature and pressure.

Not to be confused with Ethane or ETHANE. "CH4" redirects here. For other uses, see CH4 (disambiguation).

Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the atmosphere, it is known as atmospheric methane.[9]


The Earth's atmospheric methane concentration has increased by about 160% since 1750, with the overwhelming percentage caused by human activity.[10] It accounted for 20% of the total radiative forcing from all of the long-lived and globally mixed greenhouse gases, according to the 2021 Intergovernmental Panel on Climate Change report.[11] Strong, rapid and sustained reductions in methane emissions could limit near-term warming and improve air quality by reducing global surface ozone.[12]


Methane has also been detected on other planets, including Mars, which has implications for astrobiology research.[13]

Occurrence[edit]

Methane was discovered and isolated by Alessandro Volta between 1776 and 1778 when studying marsh gas from Lake Maggiore. It is the major component of natural gas, about 87% by volume. The major source of methane is extraction from geological deposits known as natural gas fields, with coal seam gas extraction becoming a major source (see coal bed methane extraction, a method for extracting methane from a coal deposit, while enhanced coal bed methane recovery is a method of recovering methane from non-mineable coal seams). It is associated with other hydrocarbon fuels, and sometimes accompanied by helium and nitrogen. Methane is produced at shallow levels (low pressure) by anaerobic decay of organic matter and reworked methane from deep under the Earth's surface. In general, the sediments that generate natural gas are buried deeper and at higher temperatures than those that contain oil.


Methane is generally transported in bulk by pipeline in its natural gas form, or by LNG carriers in its liquefied form; few countries transport it by truck.

Haynes, William M., ed. (2016). (97th ed.). CRC Press. ISBN 9781498754293.

CRC Handbook of Chemistry and Physics

at The Periodic Table of Videos (University of Nottingham)

Methane

International Chemical Safety Card 0291

United States Geological Survey (archived 6 February 2004)

Gas (Methane) Hydrates – A New Frontier

Lunsford, Jack H. (2000). "Catalytic conversion of methane to more useful chemicals and fuels: A challenge for the 21st century". Catalysis Today. 63 (2–4): 165–174. :10.1016/S0920-5861(00)00456-9.

doi

(PDF)

CDC – Handbook for Methane Control in Mining