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Chemical polarity

In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end.

"Polar molecule" and "Nonpolar" redirect here. For other uses of the term "Polar", see Polar.

Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms. Molecules containing polar bonds have no molecular polarity if the bond dipoles cancel each other out by symmetry.


Polar molecules interact through dipole-dipole intermolecular forces and hydrogen bonds. Polarity underlies a number of physical properties including surface tension, solubility, and melting and boiling points.

Nonpolar bonds generally occur when the difference in between the two atoms is less than 0.5

electronegativity

Polar bonds generally occur when the difference in electronegativity between the two atoms is roughly between 0.5 and 2.0

generally occur when the difference in electronegativity between the two atoms is greater than 2.0

Ionic bonds

This amphiphilic molecule has several polar groups (hydrophilic, water-loving) on the right side and a long nonpolar chain (lipophilic, fat-loving) at the left side. This gives it surfactant properties

This amphiphilic molecule has several polar groups (hydrophilic, water-loving) on the right side and a long nonpolar chain (lipophilic, fat-loving) at the left side. This gives it surfactant properties

A micelle – the lipophilic ends of the surfactant molecules dissolve in the oil, while the hydrophilic charged ends remain outside in the water phase, shielding the rest of the hydrophobic micelle. In this way, the small oil droplet becomes water-soluble.

A micelle – the lipophilic ends of the surfactant molecules dissolve in the oil, while the hydrophilic charged ends remain outside in the water phase, shielding the rest of the hydrophobic micelle. In this way, the small oil droplet becomes water-soluble.

Phospholipids are effective natural surfactants that have important biological functions

Phospholipids are effective natural surfactants that have important biological functions

Cross section view of the structures that can be formed by phospholipids. They can form a micelle and are vital in forming cell membranes

Cross section view of the structures that can be formed by phospholipids. They can form a micelle and are vital in forming cell membranes

Electrical deflection of water[edit]

Contrary to popular misconception, the electrical deflection of a stream of water from a charged object is not based on polarity. The deflection occurs because of electrically charged droplets in the stream, which the charged object induces. A stream of water can also be deflected in a uniform electrical field, which cannot exert force on polar molecules. Additionally, after a stream of water is grounded, it can no longer be deflected. Weak deflection is even possible for nonpolar liquids.[14]

Chemical properties

Colloid

Detergent

Electronegativities of the elements (data page)

Polar point group

Chemical Bonding

(archived)

Polarity of Bonds and Molecules

Molecule Polarity