Point reflection
In geometry, a point reflection (also called a point inversion or central inversion) is a transformation of affine space in which every point is reflected across a specific fixed point. When dealing with crystal structures and in the physical sciences the terms inversion symmetry, inversion center or centrosymmetric are more commonly used.
"Central inversion" redirects here. Not to be confused with Circle inversion.
A point reflection is an involution: applying it twice is the identity transformation. It is equivalent to a homothetic transformation with scale factor −1. The point of inversion is also called homothetic center.
An object that is invariant under a point reflection is said to possess point symmetry; if it is invariant under point reflection through its center, it is said to possess central symmetry or to be centrally symmetric. A point group including a point reflection among its symmetries is called centrosymmetric.
In Euclidean space, a point reflection is an isometry (preserves distance).[1] In the Euclidean plane, a point reflection is the same as a half-turn rotation (180° or π radians); a point reflection through the object's centroid is the same as a half-turn spin.
Terminology[edit]
The term reflection is loose, and considered by some an abuse of language, with inversion preferred; however, point reflection is widely used. Such maps are involutions, meaning that they have order 2 – they are their own inverse: applying them twice yields the identity map – which is also true of other maps called reflections. More narrowly, a reflection refers to a reflection in a hyperplane ( dimensional affine subspace – a point on the line, a line in the plane, a plane in 3-space), with the hyperplane being fixed, but more broadly reflection is applied to any involution of Euclidean space, and the fixed set (an affine space of dimension k, where ) is called the mirror. In dimension 1 these coincide, as a point is a hyperplane in the line.
In terms of linear algebra, assuming the origin is fixed, involutions are exactly the diagonalizable maps with all eigenvalues either 1 or −1. Reflection in a hyperplane has a single −1 eigenvalue (and multiplicity on the 1 eigenvalue), while point reflection has only the −1 eigenvalue (with multiplicity n).
The term inversion should not be confused with inversive geometry, where inversion is defined with respect to a circle.
Point reflection as a special case of uniform scaling or homothety[edit]
When the inversion point P coincides with the origin, point reflection is equivalent to a special case of uniform scaling: uniform scaling with scale factor equal to −1. This is an example of linear transformation.
When P does not coincide with the origin, point reflection is equivalent to a special case of homothetic transformation: homothety with homothetic center coinciding with P, and scale factor −1. (This is an example of non-linear affine transformation.)
In even-dimensional Euclidean space, say 2N-dimensional space, the inversion in a point P is equivalent to N rotations over angles π in each plane of an arbitrary set of N mutually orthogonal planes intersecting at P. These rotations are mutually commutative. Therefore, inversion in a point in even-dimensional space is an orientation-preserving isometry or direct isometry.
In odd-dimensional Euclidean space, say (2N + 1)-dimensional space, it is equivalent to N rotations over π in each plane of an arbitrary set of N mutually orthogonal planes intersecting at P, combined with the reflection in the 2N-dimensional subspace spanned by these rotation planes. Therefore, it reverses rather than preserves orientation, it is an indirect isometry.
Geometrically in 3D it amounts to rotation about an axis through P by an angle of 180°, combined with reflection in the plane through P which is perpendicular to the axis; the result does not depend on the orientation (in the other sense) of the axis. Notations for the type of operation, or the type of group it generates, are , Ci, S2, and 1×. The group type is one of the three symmetry group types in 3D without any pure rotational symmetry, see cyclic symmetries with n = 1.
The following point groups in three dimensions contain inversion:
Closely related to inverse in a point is reflection in respect to a plane, which can be thought of as a "inversion in a plane".
Inversion centers in crystallography[edit]
Molecules contain an inversion center when a point exists through which all atoms can reflect while retaining symmetry. In crystallography, the presence of inversion centers distinguishes between centrosymmetric and non-centrosymmetric compounds. Crystal structures are composed of various polyhedra, categorized by their coordination number and bond angles. For example, four-coordinate polyhedra are classified as tetrahedra, while five-coordinate environments can be square pyramidal or trigonal bipyramidal depending on the bonding angles. All crystalline compounds come from a repetition of an atomic building block known as a unit cell, and these unit cells define which polyhedra form and in what order. These polyhedra link together via corner-, edge- or face sharing, depending on which atoms share common bonds. Polyhedra containing inversion centers are known as centrosymmetric, while those without are non-centrosymmetric. Six-coordinate octahedra are an example of centrosymmetric polyhedra, as the central atom acts as an inversion center through which the six bonded atoms retain symmetry. Tetrahedra, on the other hand, are non-centrosymmetric as an inversion through the central atom would result in a reversal of the polyhedron. It is important to note that bonding geometries with odd coordination numbers must not be centrosymmetric, because these polyhedra will not contain inversion centers.
Real polyhedra in crystals often lack the uniformity anticipated in their bonding geometry. Common irregularities found in crystallography include distortions and disorder. Distortion involves the warping of polyhedra due to nonuniform bonding lengths, often due to differing electrostatic attraction between heteroatoms. For instance, a titanium center will likely bond evenly to six oxygens in an octahedra, but distortion would occur if one of the oxygens were replaced with a more electronegative fluorine. Distortions will not change the inherent geometry of the polyhedra—a distorted octahedron is still classified as an octahedron, but strong enough distortions can have an effect on the centrosymmetry of a compound. Disorder involves a split occupancy over two or more sites, in which an atom will occupy one crystallographic position in a certain percentage of polyhedra and the other in the remaining positions. Disorder can influence the centrosymmetry of certain polyhedra as well, depending on whether or not the occupancy is split over an already-present inversion center.
Centrosymmetry applies to the crystal structure as a whole, as well. Crystals are classified into thirty-two crystallographic point groups which describe how the different polyhedra arrange themselves in space in the bulk structure. Of these thirty-two point groups, eleven are centrosymmetric. The presence of noncentrosymmetric polyhedra does not guarantee that the point group will be the same—two non-centrosymmetric shapes can be oriented in space in a manner which contains an inversion center between the two. Two tetrahedra facing each other can have an inversion center in the middle, because the orientation allows for each atom to have a reflected pair. The inverse is also true, as multiple centrosymmetric polyhedra can be arranged to form a noncentrosymmetric point group.
Non-centrosymmetric compounds can be useful for application in nonlinear optics. The lack of symmetry via inversion centers can allow for areas of the crystal to interact differently with incoming light. The wavelength, frequency and intensity of light is subject to change as the electromagnetic radiation interacts with different energy states throughout the structure. Potassium titanyl phosphate, KTiOPO4 (KTP). crystalizes in the non-centrosymmetric, orthorhombic Pna21 space group, and is a useful non-linear crystal. KTP is used for frequency-doubling neodymium-doped lasers, utilizing a nonlinear optical property known as second-harmonic generation. The applications for nonlinear materials are still being researched, but these properties stem from the presence of (or lack thereof) an inversion center.
It preserves every quadratic form, meaning , and thus is an element of every as well.
